Unless otherwise specified, passivation in the present context is the chemical treatment of a stainless steel with a mild oxidant so as to remove free iron from the surface and speed up the process of forming a protectivepassive layer. Boiler preservation is required when boiler is out of service or in shutdown condition for a long period to protect boilers internal surface from corrosion and atmospheric oxygen. All boilers subject to the provisions of this act shall either 1 be continuously monitored by a mechanical or electronic devise approved by the director of the arkansas department of. Pdf the aim of chemical cleaning is to is to safely remove all. Tests with acceptance criteria to demonstrate that the passivation procedures have been successful are listed in 7.
Passivation is a chemical treatment applied to stainless steel parts to provide resistance to oxidation, rusting and mild chemical attack. This acid stage is potentially damaging to the boiler and therefore, it requires careful. What is the procedure of boiler alkali bailout, boiler. Passivation is the treatment of the surface of stainless steels, often with acid solutions or pastes, to remove contaminants and promote the formation of the passive film on a freshly created surface e. Welcome to boiler and mechanical power digital library and training videos library. Leave the test solution in the vessel until the passivation testing procedure is complete. An lng tanker was berthed alongside a shipyard, undertaking repairs to her port and starboard main boilers. Draft is the difference in pressure between two points that causes air or gases to flow. If the boiler is to be placed out of service for an extended period of time, proper layup procedures are required and must be followed. The chemical treatment leads to a protective oxide layer that is less likely to chemically react with air and cause corrosion. Fire tube boilers also referred to as smoke tube boilers, shell boilers, package boilers multiple gas paths 2, 3 and 4 pass internal furnace or fire box as the 1st pass dry back or wet back design single fuel or dual fuel design little or no steam separation equipment. Mar 25, 2018 bharat heavy electricals limitedpower sector western region recommended procedure for alkali boil out of 2 x 165 tph afbc boilers at jsl, raigarh a introduction. Standard practice for cleaning, descaling, and passivation. Sep 25, 2016 passivation the formation of a thin, nonporous layer of magnetic iron oxide on the surface of the cleaned metal in order to prevent rusting before startup.
This is a nonprofit website to share the knowledge. Circulate and spray hydrogen peroxide test solution for 30 minutes, wetting the entire surface. The advantage of hot water over steam is that energy loss is lower than with steam boilers. Preheating of the boiler isolating the unit to be cleaned from other units in the plant maintaining circulation during the cleaning process back flushing the economizer andor superheater draining the chemical solvent from the boiler filling the boiler with a passivation solution. Another plant operating a gasfired boiler system rated at 40 bar 600 psig, and producing 60 metric tons steam per hour, had been using a sodium erythorbate treatment but wanted to evaluate hydroguard i15 for possible cost savings. The chemical treatment leads to a protective oxide layer that is less likely to. Alkali boil out procedure bhel free download pdf ebook. Sep 01, 2014 the degree to which the boiler tube surfaces are truly passivated is a function of the solvent, the procedure, and the time and temperature at which the passivation is performed.
One step in the process involves the use of inhibited acid to dissolve the scales. Chemical cleaning of boiler in a thermal power plant. There are two method of boiler preservation for during boiler shutdown. Mud or bottom blowdown is usually a manual procedure done for a few seconds o. For greatest efficiency, the controlled pressure should be as close as possible to atmosphere, thereby minimizing the ingestion of tramp air or excess air drawn through the openings in the furnace ductwork that cool combustion gases. The fresh new water in boiler should be soft water and have chemical treatment. Arkansas boiler and pressure vessel law, act 494 of 1961. Acid treatment when cleaning to the opencircuit method. All slip blinds or spectacle plates utilized must be given a suitable tail or handle so immediate identification can be made in the field. Boiler preservation methods dry and wet boilersinfo.
Solvent any liquid, aqueous or nonaqueous, used to chemically clean boilers. The alkali boil out of a boiler is carried out in order to clean the internal surfaces of the watertouched parts from oil, grease, rust, silica and other adhered impurities b scope. Contaminated boiler and steam systems, as well as systems that operate at. Passivation per astm a967 uses nitric or citric acid solutions to selectively leach iron and nickel and remove contaminants, e.
Crown boiler bwf095 installation instructions manual pdf. The shutoff valve required next to the boiler on the water feed inlet, so that the entire line can be manually shut. The work included extensive retubing and air casing repairs and it was carried out by a well established boiler repair. One can reference industry standards astm a380 and astm a967 for guidance on the procedure to be followed. Preceding css link to use daily boiler helps to help you can decrease boiler are reactive and boiler clean the treatment and make sure you identify any of boiler. The aim of chemical cleaning is to is to safely remove all deposits from the inside of the boiler tubes. Steam boiler boilouts passivation boiler and pressure. View and download crown boiler bwf095 installation instructions manual online. Thermal power plant boilers kostolac b2 experience. Thermal oil boiler in hot oil boilers is used oil in stead of steam or water. However, sulfite is not considered to be a good passivating agent because it does not passivate low pressure boilers, where sulfite is most often used. The procedure for chemical cleaning includes the following steps.
There are two types of boiler preservation methods each of them is used in specific conditions. The process comprises preparing a passivation solution, and adding the passivation solution after the cleaning of the boiler is passed, and circulating at 1535 deg c for 812 hours, wherein the passivation solution comprises methanol, sodium hydrogen sulfate, hydrazine. Boiler is fired and the temperature raised to 140 deg c. Criterion for determining the success of a chemical procedure and the effectiveness of the solvent in dissolving the deposit is covered in detail. Passivation can be accomplished in high pressure boilers, but high dosages of sulfite are needed. Books covers many topics like power plants, water treatment, steam turbines, health and safety, mechanical and electrical technology.
The pitting corrosion leads to boiler tube failures and might damage. The boiler pickling and passivating process has the advantages that passivation effect is good, and film formation on the. After passivation, various tests can be performed to verify whether passivation has been properly performed. Passivation is the name applied to a number of different processes related to stainless steel. A natural draft furnace uses the stack chimney effect. A boiler is a closed vessel in which water is heated, steam is generated, superheated or any combination thereof under pressure or vacuum by the direct application of heat from combustible fuels or electricity. Chemical cleaning is a multiple stage process that seeks to remove all the existing scale from the boiler internals, leaving a clean, passivated. Manual blowdown boiler more often for the next 3 days to remove any loose scale that might have lodged at bottom of boiler. Cleaning solvents and processes were developed for application to conventional boilers. Chemical cleaning is a multiple stage process that seeks to remove all the existing scale from the boiler internals, leaving a clean, passivated waterside system. Pdf boilers and steam lines chemical cleaning researchgate. Ss passivating chemicals are domestically available, and these are used by circulating within the ss pipelines and boiler. Mar 20, 2014 major events in boiler commissioning 01.
If the boiler is to be put into service immediately, fill with water and boiler treatment, fire until the water is heated to a least 180 degrees f. The invention relates to a passivation process after chemical cleaning of a hightemperature highpressure station boiler. The passivation process provided by the invention enables a uniform and dense protective layer to grow on the inner. Boilers objectives after completing this chapter, you will be able to. The boiler commissioning activity includes the following. The passivation process removes free iron ferric material from the surface of the parts that can be created during finishing operations such as milling, buffing, lapping, cutting, etc. Deposit unwanted solid matter, which separates out of fluids in a process. This will extend the life of the vessel by protecting it from corrosion.
Start the boiler and make sure no leaks are occurring. Guidelines are also provided for operation of auxiliary equipment and appliances that affect the safe and reliable operation of power boilers. If a chelant is used, oxygen injection into the cleaning solution provides passivation. If the boiler is not going into service, refer to the bond water technologies boiler shutdown and layup procedures. A boilers efficiency is directly related to the quality of its feedwater. Cn102586772b passivation process after chemical cleaning. Describe the boiler and steam header warmup procedures. Pickling and passivation treatment boiler and pressure. Boiler tube cleaning apex engineering products corporation. Siemens high temperature process for boiler chemical cleaning, international power plant chemistry conference, eskom, 2628, november 1997. Pickling and passivation australian stainless steel. Standard practice for cleaning, descaling, and passivation of. Oxygen corrosion in boiler feedwater systems can occur during startup and shutdown and while the boiler system is on standby or in storage, if proper procedures are not followed. Boiler operation information is communicated to the boiler operator starting the shift to specify any special procedures required.
If boilers are required in stand by condition for sudden and quick demands of steam are preserved by the wet method. Before water enters the boiler, oxygen must be removed or corrosion can occur throughout the boiler system, forming pits that eat away at the metal. Edta cleaning passivation boiler ethylenediaminetetraacetic acid. The new fleet of combined cycle generating units with heat recovery. The price of deposition evaluating your boiler s health the decision to clean options summary waterside cleaning of recovery boilers. Acid cleaning operation for a natural circulation high. Systems must be stored properly to prevent corrosion damage, which can occur in a matter of hours in the absence of proper layup procedures. Passivation the formation of a thin, nonporous layer of magnetic iron oxide on. Fill the boiler with demiwater and supply steam until temperatures reaches to. In order to carry out a thorough passivation, the boiler should be chemically clean. One of the most important steps in a boilers lifetime is the initial boiler startup and.
Steam production when heat is added to water, its temperature rises at a rate of 0. Say when you talk about a boiler, carbon steel tubes in generating section will have a reduced oxide in a state of magnetite. This includes exposure to a saltspray for up to two hours, or high humidity conditions for twentyfour hours. The quality and thickness of the passive layer is however. This kind of system is suitable for discharge temperatures up to 140c. During the acid cleaning process, all the permanent boiler. Boiler is fired and the temperature raised to 140 deg c and subsequently cooled. Chapter 15 chemical cleaning of steam generator systems. If these products are not removed, corrosion will occur. This acid stage is potentially damaging to the boiler.
Boiler fundamentals steam production and steam uses steam purity and steam quality types of boilers basic boiler principles basic boiler calculations. Alkaline treatment with ammonia and passivation with hydrogen peroxide. It is a systematic procedure used after completion of erection in making the boiler and its auxiliaries. Proper commissioning and initial startup procedures extend boiler. Wet preservation of boiler dry preservation of boiler boiler preservation through. Unlike pickling, no metal is removed from the surface during acid assisted passivation. Passivation is a widelyused metal finishing process to prevent corrosion.
Passivation of stainless steel vessels for boilers is a recommended practice. Bwf series gasfired fan assisted hot water boilers. Paper mill boiler chemical cleaning why, when and how valmet. Describe the steps that must be taken to prepare a boiler for startup. Water tube boiler commissioning procedure and checklists the operation of checking the equipment and tuning them before putting into commercial operation is commonly termed as commissioning. The boiler drum pressure is raised to 40ksc and the line to be blown is warmed up. Learning objectives here is what you will be able to do when you complete each objective. Download pdf boiler commissioning procedure od4po39v09lp. In stainless steel, the passivation process uses nitric acid or citric acid to remove free iron from the surface. This procedure covers the general requirements for boiler acid cleaning based on chemical to be. The manufacturing process of the boilers is clearly a dirty process, and there is a large risk that the boilers will be contaminated with millscale,oils, or slag from the manufacture of the boiler. The cleaning mechanism and passivation on clean surface of tubes by circulation of 500 mg l1 n 2 h 4 and 0. These methods are designed to limit corrosion caused by the normal range of boiler and atmospheric contaminants.
In the decision to clean chemically and the selection of the cleaning method. Precommissioning commissioning video training part 5 10. Passivation the formation of a thin, nonporous layer of magnetic iron oxide on the surface of the cleaned metal in order to prevent rusting before startup. The composition of the passivation bath shall as be as follows. Pdf the development of standard operating procedures for. Evaluation of boiler chemical cleaning techniques international. Inspection, preoperation checking and preparation of the equipment including specialized. Pdf preoperational cleaning requirements for hrsg units.
Boiler hydro test is an erection activity and conducted after ensuring zero leakage from air leak test. Hh056 h2o2 passivation procedure page 5of 7 vessels 1. Study on construction safety in thermal power plant boiler light up, commencement power plant ward of condensor,tg erection follow procedure. Before water enters the boiler, oxygen must be removed or corrosion can occur throughout the boiler system. The arkansas boiler safety law, act 494 of 1961, section 7, provides the following.
Boiler preservation through nitrogen method is also used in power plant boilers. Operational cleaning and steam blow of large thermal power plant. Hot water boilers are normally used in room and process heating. Cn102586772b passivation process after chemical cleaning of. Normal operating water levelthe most important task in. The boiler is lighted up and pressured is raised to 40 kg per cm2 the sample is to be tested for hydrazine concentration and should not be less than 25 ppm after 24 hours fire should be killed and boxed up open super heater vent at 90c and boiler is drained, the second stage passivation marks completion of chemical cleaning 8 passivation. Solvay chemicals technical publication 2 passivation. Refractory dry out air tightness test gas tightness test alkali boil out passivation steam blowing.
Feb 16, 20 edta cleaning processalkali flushing procedure alkali flushing alkali solution made by adding tsp0. This paper describes the accelerated program for the development of standard operating procedures for boilers following a significant incident during. A boiler s efficiency is directly related to the quality of its feedwater. In this process the mixture of chemical solutions containing edta, inhibitor, ammonia and hydrazine in dm water is filled in the boiler. Edta cleaning processalkali flushing procedure alkali flushing alkali solution made by adding tsp0. This plant was able to save money by switching from hydrazine to hydroguard i15. Edta cleaning passivation free download as powerpoint presentation. The feedwater system refers to deaerator, feedwater pumps, and the piping to the boiler. Follow the passivation testing procedure in figure 2.
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